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Structural Isomerism have the same molecular formula but different molecular structures, i.e. the atoms are bonded together in a different sequence.
Homolytic fission
The Bond breaks evenly with one electron from the bonding pair going to each atom A° °B This produces species with single electrons called free radicals. Free radicals are most commonly formed when the bond being broken has electrons that are fairly equally shared.
Heterolytic fission
In Heterolytic bond fission, when the bond breaks, both of the shared pair of electrons go to just one of the atoms. Heterolytic fission is more common where a bond is already polar...
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