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Rheological behavior is shown to be strongly influenced by clay loading and the extent of clay dispersion in the polymer matrix. Transition from liquid-like behavior to solid-like behavior shifts to significantly higher solids loading at higher shear rates which may be due to the alignment of the particles in the direction of flow at high shear rates. SEM micrographs are used to display the extent of intercalation and dispersion of the clay within the polymer matrix.
INTRODUCTION AND BACKGROUND
Polymer/clay nanocomposites display a change in composition and structure over a nanometer length scale and have been shown to present considerable property enhancements relative to conventionally scaled composites...
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