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It is known as a spontaneous reaction not because it happens spontaneously but because it requires initial energy in order for the reaction to take place and the products have less energy than the reactants.
An active site occurs in the enzyme because a few of the amino acids on the surface of the 3d molecule fold inwards thus creating an indention in the enzyme. The ?lock and key hypothesis' uses this analogy due to the fact that only one substrate fits one particular active site. This is because simply the substrate and active site both contain certain elements that will only product certain temporary bonds with particular other elements...
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