|Date:||January 16, 2012|
|Length:||2 / 582|
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Consequently, when used as a basis for the discussion of chemistry, the charge density allows for a direct physical picture and interpretation.
In particular, the forces exerted on a nucleus in a molecule by the other nuclei and by the electronic charge density may be rigorously calculated and interpreted in terms of classical electrostatics...
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Thus, given the molecular charge distribution, the stability of a chemical bond may be discussed in terms of the electrostatic requirement of achieving a zero force on the nuclei in the molecule. A chemical bond is the result of the accumulation of negative charge density in the region between any pair of nuclei to an extent sufficient to balance the forces of repulsion...
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